Please use this identifier to cite or link to this item:
https://doi.org/10.1021/acs.jpclett.5b01164
DC Field | Value | |
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dc.title | Anomalous behavior of the homogeneous ice nucleation rate in "no-man's land" | |
dc.contributor.author | Laksmono, H | |
dc.contributor.author | McQueen, T.A | |
dc.contributor.author | Sellberg, J.A | |
dc.contributor.author | Loh, N.D | |
dc.contributor.author | Huang, C | |
dc.contributor.author | Schlesinger, D | |
dc.contributor.author | Sierra, R.G | |
dc.contributor.author | Hampton, C.Y | |
dc.contributor.author | Nordlund, D | |
dc.contributor.author | Beye, M | |
dc.contributor.author | Martin, A.V | |
dc.contributor.author | Barty, A | |
dc.contributor.author | Seibert, M.M | |
dc.contributor.author | Messerschmidt, M | |
dc.contributor.author | Williams, G.J | |
dc.contributor.author | Boutet, S | |
dc.contributor.author | Amann-Winkel, K | |
dc.contributor.author | Loerting, T | |
dc.contributor.author | Pettersson, L.G.M | |
dc.contributor.author | Bogan, M.J | |
dc.contributor.author | Nilsson, A | |
dc.date.accessioned | 2020-11-23T08:55:08Z | |
dc.date.available | 2020-11-23T08:55:08Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | Laksmono, H, McQueen, T.A, Sellberg, J.A, Loh, N.D, Huang, C, Schlesinger, D, Sierra, R.G, Hampton, C.Y, Nordlund, D, Beye, M, Martin, A.V, Barty, A, Seibert, M.M, Messerschmidt, M, Williams, G.J, Boutet, S, Amann-Winkel, K, Loerting, T, Pettersson, L.G.M, Bogan, M.J, Nilsson, A (2015). Anomalous behavior of the homogeneous ice nucleation rate in "no-man's land". Journal of Physical Chemistry Letters 6 (14) : 2826-2832. ScholarBank@NUS Repository. https://doi.org/10.1021/acs.jpclett.5b01164 | |
dc.identifier.issn | 1948-7185 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/183882 | |
dc.description.abstract | We present an analysis of ice nucleation kinetics from near-ambient pressure water as temperature decreases below the homogeneous limit T<inf>H</inf> by cooling micrometer-sized droplets (microdroplets) evaporatively at 103-104 K/s and probing the structure ultrafast using femtosecond pulses from the Linac Coherent Light Source (LCLS) free-electron X-ray laser. Below 232 K, we observed a slower nucleation rate increase with decreasing temperature than anticipated from previous measurements, which we suggest is due to the rapid decrease in water's diffusivity. This is consistent with earlier findings that microdroplets do not crystallize at <227 K, but vitrify at cooling rates of 106-107 K/s. We also hypothesize that the slower increase in the nucleation rate is connected with the proposed "fragile-to-strong" transition anomaly in water. © 2015 American Chemical Society. | |
dc.publisher | American Chemical Society | |
dc.rights | Attribution 4.0 International | |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
dc.source | Unpaywall 20201031 | |
dc.subject | Diffusion | |
dc.subject | Electromagnetic pulse | |
dc.subject | Electrons | |
dc.subject | Free electron lasers | |
dc.subject | Light sources | |
dc.subject | Nucleation | |
dc.subject | X ray lasers | |
dc.subject | Fragile-to-strong liquid transition | |
dc.subject | Ice nucleation | |
dc.subject | Ice nucleation rates | |
dc.subject | Linac Coherent Light Source | |
dc.subject | Supercooled water | |
dc.subject | Temperature decrease | |
dc.subject | Transition anomalies | |
dc.subject | X-ray free electron lasers | |
dc.subject | Ice | |
dc.type | Article | |
dc.contributor.department | DEPT OF PHYSICS | |
dc.description.doi | 10.1021/acs.jpclett.5b01164 | |
dc.description.sourcetitle | Journal of Physical Chemistry Letters | |
dc.description.volume | 6 | |
dc.description.issue | 14 | |
dc.description.page | 2826-2832 | |
dc.published.state | published | |
Appears in Collections: | Staff Publications Elements |
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