Please use this identifier to cite or link to this item: https://doi.org/10.1107/S2056989015003473
DC FieldValue
dc.titleCrystal structure of tri-chlorido-(4'-ferrocenyl-2,2':6',2''-terpyridine-κ(3) N,N',N'')iridium(III) aceto-nitrile disolvate
dc.contributor.authorDavaasuren, B
dc.contributor.authorPadhy, H
dc.contributor.authorRothenberger, A
dc.contributor.authorWeil, M
dc.date.accessioned2020-10-26T08:30:43Z
dc.date.available2020-10-26T08:30:43Z
dc.date.issued2015
dc.identifier.citationDavaasuren, B, Padhy, H, Rothenberger, A, Weil, M (2015). Crystal structure of tri-chlorido-(4'-ferrocenyl-2,2':6',2''-terpyridine-κ(3) N,N',N'')iridium(III) aceto-nitrile disolvate. Acta Crystallographica Section E: Structure Reports Online 71 (3) : m69-m70. ScholarBank@NUS Repository. https://doi.org/10.1107/S2056989015003473
dc.identifier.issn16005368
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/180341
dc.description.abstractIn the title compound, [FeIr(C5H5)(C20H14N3) Cl3]·2CH3CN, the central IrIII atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octahedral fashion. The terpyridine ligand is functionalized at the 40 -position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, molecules are stacked in rows parallel to [001], with the acetonitrile solvent molecules situated between the rows. An extensive network of intra- and intermolecular C - H?Cl interactions is present, stabilizing the three-dimensional structure.
dc.rightsAttribution 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.sourceUnpaywall 20201031
dc.typeArticle
dc.contributor.departmentMECHANICAL ENGINEERING
dc.description.doi10.1107/S2056989015003473
dc.description.sourcetitleActa Crystallographica Section E: Structure Reports Online
dc.description.volume71
dc.description.issue3
dc.description.pagem69-m70
dc.published.statePublished
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