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https://scholarbank.nus.edu.sg/handle/10635/171378
| Title: | EFFECTS OF SUBSTITUENTS ON THE ALKALINE CLEAVAGE OF BENZYL-SILICON BONDS | Authors: | YAP BEI SING | Issue Date: | 1972 | Citation: | YAP BEI SING (1972). EFFECTS OF SUBSTITUENTS ON THE ALKALINE CLEAVAGE OF BENZYL-SILICON BONDS. ScholarBank@NUS Repository. | Abstract: | The compound Bis-(trimethylsilyl)-m-chlorophenylmethane has been prepared. The kinetics of the alkaline cleavage of this compound in DMSO-water (6:1, V/V) has been studied Spectrophotometrically at 30°C. The rate of cleavage by 0.01 N NaOH is 1.01 x 10-4 sec-1 with a half-life of 114.6 min. and that by 0.05 N NaOH is 3.29 x 10-3 sec-1 with a half-life of 3.51 min. | URI: | https://scholarbank.nus.edu.sg/handle/10635/171378 |
| Appears in Collections: | Bachelor's Theses |
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