Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201811067
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dc.titleA Cross-linked Conjugated Polymer Photosensitizer Enables Efficient Sunlight-Induced Photooxidation
dc.contributor.authorWu, Wenbo
dc.contributor.authorXu, Shidang
dc.contributor.authorQi, Guobin
dc.contributor.authorZhu, Han
dc.contributor.authorHu, Fang
dc.contributor.authorLiu, Zitong
dc.contributor.authorZhang, Deqing
dc.contributor.authorLiu, Bin
dc.date.accessioned2020-06-12T08:10:47Z
dc.date.available2020-06-12T08:10:47Z
dc.date.issued2019-03-04
dc.identifier.citationWu, Wenbo, Xu, Shidang, Qi, Guobin, Zhu, Han, Hu, Fang, Liu, Zitong, Zhang, Deqing, Liu, Bin (2019-03-04). A Cross-linked Conjugated Polymer Photosensitizer Enables Efficient Sunlight-Induced Photooxidation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58 (10) : 3062-3066. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201811067
dc.identifier.issn14337851
dc.identifier.issn15213773
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/169702
dc.description.abstract© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Photooxidation under sunlight has potential in organic synthesis, bacterial killing, and organic waste treatment. Photosensitizers (PSs) can play an important role in this process. High 1 O 2 generation efficiency and excellent photostability under sunlight, as well as easy recyclability are ideal properties for PSs, but are not easy to achieve simultaneously. Herein, a pure organic porous conjugated polymer PS, CPTF, shows great photostability, large specific surface area, and high 1 O 2 generation efficiency under sunlight for photooxidation. For the oxidation of aromatic aldehyde to aromatic acid, the PS catalyst shows excellent recyclability, and enables solvent-free reactions in high yields both under direct sunlight and simulated AM 1.5G irradiation. In addition, the successful application of CPTF as an antibacterial agent and organic waste decomposition under simulated AM 1.5G irradiation indicates the potential of CPTF in sunlight-induced waste water treatment.
dc.language.isoen
dc.publisherWILEY-V C H VERLAG GMBH
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectantibacterial agents
dc.subjectphotooxidation
dc.subjectphotosensitizers
dc.subjectsunlight-induced organic synthesis
dc.subjectsunlight-induced wastewater treatment
dc.subjectAGGREGATION-INDUCED EMISSION
dc.subjectSELECTIVE OXIDATION
dc.subjectPHOTOCATALYTIC ACTIVITY
dc.subjectALCOHOLS
dc.typeArticle
dc.date.updated2020-06-11T07:40:59Z
dc.contributor.departmentDEPT OF CHEMICAL & BIOMOLECULAR ENGG
dc.description.doi10.1002/anie.201811067
dc.description.sourcetitleANGEWANDTE CHEMIE-INTERNATIONAL EDITION
dc.description.volume58
dc.description.issue10
dc.description.page3062-3066
dc.published.statePublished
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