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|Title:||Surface modification studies of edge-oriented molybdenum sulfide nanosheets||Authors:||Zhang, H.
|Issue Date:||3-Aug-2004||Citation:||Zhang, H., Loh, K.P., Sow, C.H., Gu, H., Su, X., Huang, C., Chen, Z.K. (2004-08-03). Surface modification studies of edge-oriented molybdenum sulfide nanosheets. Langmuir 20 (16) : 6914-6920. ScholarBank@NUS Repository. https://doi.org/10.1021/la049887t||Abstract:||We have synthesized edge-oriented MoS 2 nanoaheets by the evaporation of a single source precursor based on Mo(IV)- tetrakis(diethylaminodithiocarbomato). The surface chemistry of the MoS 2 nanosheets has been studied in order to evaluate the chemical reactivities of the basal planes and edges. By irradiating the MoS 2 nanosheet with a scanning infrared laser, micron-scale lithographical structures can be created due to laser-induced oxidation of MoS 2 to form nanocrystalline MoS 2. Preferential reactivities of the MoS 2 basal edges in an electrochemical environment and during vapor phase deposition have been demonstrated. Functionalization of the basal plane with 1-pyrene acetic acid allows the immobilization of DNA and immunoglobins on the MoS 2 basal plane.||Source Title:||Langmuir||URI:||http://scholarbank.nus.edu.sg/handle/10635/115959||ISSN:||07437463||DOI:||10.1021/la049887t|
|Appears in Collections:||Staff Publications|
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