Syntheses and structures of Group 12 metal thioacetate anions, [M(SC{O}Me)nCl4-n]2- (n=3 and 4) and [Cd2Cl2(SC{O}Me)4]2-

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0020-1693(02)00731-4

Title:	Syntheses and structures of Group 12 metal thioacetate anions, [M(SC{O}Me)nCl4-n]2- (n=3 and 4) and [Cd2Cl2(SC{O}Me)4]2-
Authors:	Valan Amburose, C. Deivaraj, T.C. Lai, G.X. Sampanthar, J.T. Vittal, J.J.
Keywords:	Crystal structures Group 12 metal complexes Thioacetate complexes
Issue Date:	17-Apr-2002
Citation:	Valan Amburose, C.,Deivaraj, T.C.,Lai, G.X.,Sampanthar, J.T.,Vittal, J.J. (2002-04-17). Syntheses and structures of Group 12 metal thioacetate anions, [M(SC{O}Me)nCl4-n]2- (n=3 and 4) and [Cd2Cl2(SC{O}Me)4]2-. Inorganica Chimica Acta 332 (1) : 160-166. ScholarBank@NUS Repository. https://doi.org/10.1016/S0020-1693(02)00731-4
Abstract:	We have utilized the possibility of altering the ratio of reactants to result in tetrahedral anions, [M(SC{O}Me)nCl4-n]2- (n=3, 4) and [Cd2Cl2(SC{O}Me)4]2-. Complexes of the formula [Ph4P]2[M(SC{O}Me)4] (M=Zn(II) (1), Cd(II) (2) or Hg(II) (3)) were synthesized by the reaction of thioacetate ligand with the metal salts and Ph4PCl in 4:1:2 molar ratio in suitable solvents. The geometry of Zn(II) in 1 is nearly tetrahedral and the distortion in tetrahedron increases in the order of 1
Source Title:	Inorganica Chimica Acta
URI:	http://scholarbank.nus.edu.sg/handle/10635/113210
ISSN:	00201693
DOI:	10.1016/S0020-1693(02)00731-4
Appears in Collections:	Staff Publications

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