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|Title:||Non-oxidative conversion of methane to aromatics over modified Mo/HZSM5 catalysts|
|Authors:||Tang, S. |
Non-oxidative conversion of methane
|Citation:||Tang, S.,Chen, H.,Lin, J.,Tan, K.L. (2001). Non-oxidative conversion of methane to aromatics over modified Mo/HZSM5 catalysts. Catalysis Communications 2 (1) : 31-35. ScholarBank@NUS Repository.|
|Abstract:||The effects of HZSM5 Si/Al ratio, cobalt additive and HCl-acidified pretreatment on methane conversion and selectivity to aromatics have been investigated for non-oxidative conversion of methane to aromatics. The HZSM5 (E) with low Si/Al ratio (Si/Al = 20) has better methane conversion and benzene selectivity than HZSM5 (D) (Si/Al = 55). The synergistic effect is exhibited in 3% Mo-1% Co-HCl/HZSM5 (E) catalyst, on which a high methane conversion of 10.7% can be achieved, in comparison with 5.3% methane conversion on 3% Mo/HZSM5 (E). The catalysts have been characterized by XPS and the reaction mechanism is discussed. © 2001 Published by Elsevier Science B.V. All rights reserved.|
|Source Title:||Catalysis Communications|
|Appears in Collections:||Staff Publications|
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