Please use this identifier to cite or link to this item:
|Title:||Thiophene-2,5-dicarboxylic acid incorporated self-assembly of one-, two- and three-dimensional coordination polymers|
|Source:||Chen, B.-L., Mok, K.-F., Ng, S.-C., Drew, M.G.B. (1999). Thiophene-2,5-dicarboxylic acid incorporated self-assembly of one-, two- and three-dimensional coordination polymers. New Journal of Chemistry 23 (8) : 877-883. ScholarBank@NUS Repository. https://doi.org/10.1039/a901688k|
|Abstract:||Six thiophene-2,5-dicarboxylic acid incorporated and self-assembled zinc(II), cobalt(II) and manganese(II) coordination polymers [Zn(Tda)(py)](n) (1), [Zn(Tda)(bipy)(H2O)·1.5H2O](n) (2), [Zn(Tda)(phen)(H2O)](n) (3), [Co(Tda)(phen)(H2O)](n) (4), [Mn(Tda)(phen)](n) (5) and [Mn(Tda)(H2O)2](n) (6) have been synthesised and structurally characterised. Complex 1 is characterised as a two-dimensional parallelogram with a cavity of about 10.4 x 10.4 Å, while complexes 2 and 3 (4) are one-dimensional linear and zig-zag coordination polymers with mainly hydrogen-bonding and stacking interactions contributing to their crystal packing, respectively. Complex 5 is a two- dimensional porous sheet with alternating 16- and 8-membered rings, while complex 6 is a three-dimensional porous coordination polymer. The diverse coordination properties of thiophene-2,5-dicarboxylate make it a good building block for the construction of coordination polymers of different architectures, which are dependent on both the end-capping ligand and the coordination geometry of the metal ions. Physical and thermal properties of these complexes have also been studied.|
|Source Title:||New Journal of Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 15, 2018
WEB OF SCIENCETM
checked on Feb 5, 2018
checked on Feb 19, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.