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|Title:||Synthetic, spectroscopic and HLPC studies of some substituted osmium clusters containing pentafluorobenzoate ligand|
|Authors:||Ang, H.G. |
|Citation:||Ang, H.G.,Kwik, W.L.,Morrison, E. (1991-01). Synthetic, spectroscopic and HLPC studies of some substituted osmium clusters containing pentafluorobenzoate ligand. Journal of Fluorine Chemistry 51 (1) : 83-91. ScholarBank@NUS Repository.|
|Abstract:||Reactions of pentafluorobenzoic acid with Os3(CO)10(CH3CN)2 and Os3(CO)11(CH3CN) afforded two new carboxylate triosmium carbonyl clusters viz. Os3(CO)10H(γ-C6F5CO2) and Os3(CO)11H(uC6F5CO2) respectively. I.r. and 1H n.m.r spectral data suggest that the pentafluorobenzoate acts as a bridging ligand in one case and as a unidentate ligand in the other. © 1991.|
|Source Title:||Journal of Fluorine Chemistry|
|Appears in Collections:||Staff Publications|
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