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https://scholarbank.nus.edu.sg/handle/10635/95187
| Title: | Synthetic, spectroscopic and HLPC studies of some substituted osmium clusters containing pentafluorobenzoate ligand | Authors: | Ang, H.G. Kwik, W.L. Morrison, E. |
Issue Date: | Jan-1991 | Citation: | Ang, H.G.,Kwik, W.L.,Morrison, E. (1991-01). Synthetic, spectroscopic and HLPC studies of some substituted osmium clusters containing pentafluorobenzoate ligand. Journal of Fluorine Chemistry 51 (1) : 83-91. ScholarBank@NUS Repository. | Abstract: | Reactions of pentafluorobenzoic acid with Os3(CO)10(CH3CN)2 and Os3(CO)11(CH3CN) afforded two new carboxylate triosmium carbonyl clusters viz. Os3(CO)10H(γ-C6F5CO2) and Os3(CO)11H(uC6F5CO2) respectively. I.r. and 1H n.m.r spectral data suggest that the pentafluorobenzoate acts as a bridging ligand in one case and as a unidentate ligand in the other. © 1991. | Source Title: | Journal of Fluorine Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95187 | ISSN: | 00221139 |
| Appears in Collections: | Staff Publications |
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