Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0022-328X(02)02120-4
Title: Synthesis, NMR and structural studies of cluster derivatives derived from reactions of 1,2,3-triphenyl-1,2,3-triphosphaindan with [Os3(CO)10(μ-H)2]
Authors: Ang, S.-G. 
Zhong, X. 
Ang, H.-G. 
Keywords: 31P-NMR
Crystal structures
Osmium cluster
Triphosphaindan
Issue Date: 3-Jan-2003
Citation: Ang, S.-G., Zhong, X., Ang, H.-G. (2003-01-03). Synthesis, NMR and structural studies of cluster derivatives derived from reactions of 1,2,3-triphenyl-1,2,3-triphosphaindan with [Os3(CO)10(μ-H)2]. Journal of Organometallic Chemistry 665 (1-2) : 218-225. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(02)02120-4
Abstract: Reactions of 1,2,3-triphenyl-1,2,3-triphosphaindan (I) with [Os3(CO)10(μ-H)2] at various conditions afford a series of osmium carbonyl cluster derivatives: an open bent-chain trinuclear cluster [Os3(CO)9{μ3- η3-PPhC6H4(PPh)2}] (1), a di-substituted bridged trinuclear cluster [Os3(CO)10 {μ-1,3-η2-C6H4(PPh)3}] (2), a 1,3-linked bis-trinuclear hydride cluster {μ3-η3-{(PPh)2C6H 4PPh}] (4), and a closed trinuclear cluster [(μ-H)Os3 (CO)8{C6H4(PPh)3}{μ-η 3-{C6H4(PPh)2PC6 H4}] (5). All the compounds obtained have been fully characterized by spectroscopic methods (IR, FABMS, 1H- and 31P-NMR spectroscopy), and the molecular structures of 3, 4, 5 are established by X-ray crystallography. © 2002 Elsevier Science B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/95162
ISSN: 0022328X
DOI: 10.1016/S0022-328X(02)02120-4
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

6
checked on May 21, 2018

WEB OF SCIENCETM
Citations

6
checked on Apr 30, 2018

Page view(s)

39
checked on May 4, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.