Synthesis, and spectral and X-ray structural studies of a novel delocalised triphosphazene (CF3)2PNP(CF3) 2NPPh3 and the triosmium cluster complex Os3(CO)11[(CF3)2PNP(CF3)2NPPh3]

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/95136

Title:	Synthesis, and spectral and X-ray structural studies of a novel delocalised triphosphazene (CF3)2PNP(CF3) 2NPPh3 and the triosmium cluster complex Os3(CO)11[(CF3)2PNP(CF3)2NPPh3]
Authors:	Ang, H.G. Cai, Y.M. Kwik, W.L.
Issue Date:	20-Apr-1993
Citation:	Ang, H.G.,Cai, Y.M.,Kwik, W.L. (1993-04-20). Synthesis, and spectral and X-ray structural studies of a novel delocalised triphosphazene (CF3)2PNP(CF3) 2NPPh3 and the triosmium cluster complex Os3(CO)11[(CF3)2PNP(CF3)2NPPh3]. Journal of Organometallic Chemistry 448 (1-2) : 219-223. ScholarBank@NUS Repository.
Abstract:	The triphosphazene (CF3)2PNP(CF3)2NPPh3 (L), prepared by the reaction of (CF3)2PN3 with (CF3)2PNPPh3, has been found to afford the cluster [Os3(CO)11{(CF3)2PNP(CF3)2NPPh3}] (1) with [Os3(CO)11(MeCN)]. Both L and 1 have been shown by X-ray crystallography to have an unusual and highly delocalised PNPNP moiety containing PIV, PV and PVI atoms. © 1992.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/95136
ISSN:	0022328X
Appears in Collections:	Staff Publications

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