Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.200900133
Title: Synthesis of aryl sulfides by decarboxylative C-S cross-couplings
Authors: Duan, Z. 
Ranjit, S.
Zhang, P.
Liu, X. 
Keywords: Carboxylic acid
Cross-coupling
Decarboxylation reaction
Thiols
Transition metals
Issue Date: 6-Apr-2009
Citation: Duan, Z., Ranjit, S., Zhang, P., Liu, X. (2009-04-06). Synthesis of aryl sulfides by decarboxylative C-S cross-couplings. Chemistry - A European Journal 15 (15) : 3666-3669. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.200900133
Abstract: A study was conducted to demonstrate the transition-metal-catalyzed synthesis of aryl sulfides by decarboxylative C-S cross-couplings. Coupling reaction of 2-nitrobenzoic acid with 1-octanethiol were carried in the presence of different combinations of transition-metal catalysts at elevated temperatures to investigate the synthesis process and identify an effective catalyst system. The investigations showed that these reactions formed decarboxylative coupling products containing a mixture of nitrobenzene and aminobenzene sulfides. It was also demonstrated that reactions conducted with monometallic PdII, CuII, or bimetallic CuII, AgI, PdII, and AgI catalysts resulted in low conversions of starting materials. A wide range of aryl carboxylic acids were tested as substrates for C-S coupling to expand the scope of the method.
Source Title: Chemistry - A European Journal
URI: http://scholarbank.nus.edu.sg/handle/10635/95115
ISSN: 09476539
DOI: 10.1002/chem.200900133
Appears in Collections:Staff Publications

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