Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.200900133
Title: Synthesis of aryl sulfides by decarboxylative C-S cross-couplings
Authors: Duan, Z. 
Ranjit, S.
Zhang, P.
Liu, X. 
Keywords: Carboxylic acid
Cross-coupling
Decarboxylation reaction
Thiols
Transition metals
Issue Date: 6-Apr-2009
Citation: Duan, Z., Ranjit, S., Zhang, P., Liu, X. (2009-04-06). Synthesis of aryl sulfides by decarboxylative C-S cross-couplings. Chemistry - A European Journal 15 (15) : 3666-3669. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.200900133
Abstract: A study was conducted to demonstrate the transition-metal-catalyzed synthesis of aryl sulfides by decarboxylative C-S cross-couplings. Coupling reaction of 2-nitrobenzoic acid with 1-octanethiol were carried in the presence of different combinations of transition-metal catalysts at elevated temperatures to investigate the synthesis process and identify an effective catalyst system. The investigations showed that these reactions formed decarboxylative coupling products containing a mixture of nitrobenzene and aminobenzene sulfides. It was also demonstrated that reactions conducted with monometallic PdII, CuII, or bimetallic CuII, AgI, PdII, and AgI catalysts resulted in low conversions of starting materials. A wide range of aryl carboxylic acids were tested as substrates for C-S coupling to expand the scope of the method.
Source Title: Chemistry - A European Journal
URI: http://scholarbank.nus.edu.sg/handle/10635/95115
ISSN: 09476539
DOI: 10.1002/chem.200900133
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

127
checked on Aug 16, 2018

WEB OF SCIENCETM
Citations

125
checked on Jul 31, 2018

Page view(s)

44
checked on Aug 3, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.