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|Title:||Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine|
|Authors:||Ang, H.G. |
|Citation:||Ang, H.G.,Kwik, W.L.,Leong, W.K.,Johnson, B.F.G.,Lewis, J.,Raithby, P.R. (1990-10-16). Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine. Journal of Organometallic Chemistry 396 (2-3) : C43-C46. ScholarBank@NUS Repository.|
|Abstract:||The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle. © 1990.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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