Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/95110

Title:	Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine
Authors:	Ang, H.G. Kwik, W.L. Leong, W.K. Johnson, B.F.G. Lewis, J. Raithby, P.R.
Issue Date:	16-Oct-1990
Citation:	Ang, H.G.,Kwik, W.L.,Leong, W.K.,Johnson, B.F.G.,Lewis, J.,Raithby, P.R. (1990-10-16). Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine. Journal of Organometallic Chemistry 396 (2-3) : C43-C46. ScholarBank@NUS Repository.
Abstract:	The reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle. © 1990.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/95110
ISSN:	0022328X
Appears in Collections:	Staff Publications

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