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|Title:||Synthesis and coordinating properties of (o-diphenylphosphinobenzyl)dimethylsilane|
|Authors:||Ang, H.G. |
|Source:||Ang, H.G.,Lau, P.T. (1985-08-27). Synthesis and coordinating properties of (o-diphenylphosphinobenzyl)dimethylsilane. Journal of Organometallic Chemistry 291 (3) : 285-291. ScholarBank@NUS Repository.|
|Abstract:||The reactions of (o-diphenylphosphinobenzyl)dimethylsilane with manganese and rhenium carbonyl afford o-(C6H5)2PC6H4CH 2Si(CH3)2Mn(CO)4 (M = Mn, Re), in which the ligand behaves as a chelate. Similar reactions occur with π-cyclopentadienemolybdenum tricarbonyl dimer to give o-(C6H5)2PC6H4 CH2Si(CH3)2Mo(π- C5H5)(CO)2. However, photolysis of a mixture of the ligand with manganese carbonyl yielded o-(C6H5)2PC6H4 CH2Si(H)(CH3)2Mn2(CO) 9. © 1985.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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