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|Title:||Syntheses and characterization of electrically conductive and fluorescent poly[3-(ω-bromoalkyl)thiophenes]|
|Authors:||Ng, S.C. |
|Citation:||Ng, S.C., Ma, Y.F., Chan, H.S.O., Dou, Z.L. (1999-04-26). Syntheses and characterization of electrically conductive and fluorescent poly[3-(ω-bromoalkyl)thiophenes]. Synthetic Metals 100 (3) : 269-277. ScholarBank@NUS Repository. https://doi.org/10.1016/S0379-6779(98)01496-9|
|Abstract:||A novel series of functionalized polythiophenes incorporating 3-(ω-bromoalkyl) pendants were synthesized by chemical oxidative polymerization using FeCl3 and characterized using FT-IR, UV-Vis absorption spectroscopy, fluorescence emission spectroscopy, conductivity measurements and thermal analyses. These polymers attained a maximum electrical conductivity between 4.7 and 8.4 S cm-1 upon doping with iodine and have a fluorescence quantum yield of up to 11.1% with respect to quinine sulfate. The influence of the terminal ω-bromine substituent as of the length of the alkyl pendant on electrical conductivity, spectral behavior and thermal stability is discussed.|
|Source Title:||Synthetic Metals|
|Appears in Collections:||Staff Publications|
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