Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2003.09.028
Title: Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex
Authors: Weng, Z. 
Koh, L.L. 
Hor, T.S.A. 
Keywords: 1,1′-Ferrocenediyl
Aqueous
Catalysis
Palladium
Suzuki coupling
Issue Date: 5-Jan-2004
Citation: Weng, Z., Koh, L.L., Hor, T.S.A. (2004-01-05). Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex. Journal of Organometallic Chemistry 689 (1) : 18-24. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2003.09.028
Abstract: Reaction of PdCl2(MeCN)2 with Fe[η-C5H4NC(H)Ph-N]2 (1) at MeOH at r.t. gives air-stable PdCl2Fe[η-C5 H4NC(H)Ph-N]2 (2; yield 84%). X-ray single-crystal diffraction analyses show that 2 is a Pd(II) square planar complex with N,N′ chelation of the ferrocenediyl ligand, without Fe-Pd bond. It effectively catalyzes Suzuki cross-coupling reactions of aryl iodides and bromides with aryl boronic acids in aqueous media under non-homogeneous conditions in which the products can be easily isolated. The reaction conditions including choice of base, catalytic load and catalyst recoverability have been investigated and reported. © 2003 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94994
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2003.09.028
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

42
checked on Sep 12, 2018

WEB OF SCIENCETM
Citations

37
checked on Sep 4, 2018

Page view(s)

25
checked on Mar 11, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.