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https://scholarbank.nus.edu.sg/handle/10635/94901
| Title: | Structural characterisation of the elusive isomer of Os3(CO)10(PPh3)2 | Authors: | Leong, W.K. Liu, Y. |
Keywords: | Clusters Isomers Osmium Phosphine |
Issue Date: | 10-Jul-1999 | Citation: | Leong, W.K.,Liu, Y. (1999-07-10). Structural characterisation of the elusive isomer of Os3(CO)10(PPh3)2. Journal of Organometallic Chemistry 584 (1) : 174-178. ScholarBank@NUS Repository. | Abstract: | The X-ray crystal structure of the elusive isomer of Os3(CO)10(PPh3)2 in which the two phosphine ligands are cis and trans with respect to the phosphine-substituted Os-Os edge has been determined; the first direct confirmation for the existence of this isomer in Os3(CO)10(PR3)2 clusters. In contrast to the trans,trans isomer, the cis,trans isomer shows little twisting of the Os(CO)3(PPh3) groupings with respect to the Os(CO)4 unit. © 1999 Elsevier Science S.A. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94901 | ISSN: | 0022328X |
| Appears in Collections: | Staff Publications |
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