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|Title:||Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl2]2: A computational and experimental study|
|Citation:||Sridevi, V.S., Wai, Y.F., Weng, K.L. (2007-02-26). Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl2]2: A computational and experimental study. Organometallics 26 (5) : 1157-1160. ScholarBank@NUS Repository. https://doi.org/10.1021/om0609158|
|Abstract:||The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl 2]2 to afford selectively the β-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed. © 2007 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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