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https://doi.org/10.1021/om0609158
| Title: | Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl2]2: A computational and experimental study | Authors: | Sridevi, V.S. Wai, Y.F. Weng, K.L. |
Issue Date: | 26-Feb-2007 | Citation: | Sridevi, V.S., Wai, Y.F., Weng, K.L. (2007-02-26). Stereoselective hydrosilylation of terminal alkynes catalyzed by [Cp*IrCl2]2: A computational and experimental study. Organometallics 26 (5) : 1157-1160. ScholarBank@NUS Repository. https://doi.org/10.1021/om0609158 | Abstract: | The hydrosilylation of terminal alkynes is catalyzed by [Cp*IrCl 2]2 to afford selectively the β-(Z)-vinylsilanes in high yields. A catalytic cycle based on an Ir(III)-Ir(V) redox process is proposed. © 2007 American Chemical Society. | Source Title: | Organometallics | URI: | http://scholarbank.nus.edu.sg/handle/10635/94883 | ISSN: | 02767333 | DOI: | 10.1021/om0609158 |
| Appears in Collections: | Staff Publications |
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