Please use this identifier to cite or link to this item:
|Title:||Spacer-directed coordination polymers-of-oligomers (POLO) of silver|
Andy Hör, T.S.
|Citation:||Teo, P., Koh, L.L., Andy Hör, T.S. (2008-10-20). Spacer-directed coordination polymers-of-oligomers (POLO) of silver. Inorganic Chemistry 47 (20) : 9561-9568. ScholarBank@NUS Repository. https://doi.org/10.1021/ic801311j|
|Abstract:||A novel series of Ag(I) polymers-of-oligomers with pyridylcarboxylate spacers supported by a diphosphine [1,1′-bis(diphenylphosphino)methane (dppm) or 1,1′-bis(diphenylphosphino)ferrocene (dppf)] has been constructed and crystallographically established. The repeating oligomeric Ag5 block is invariably made up of five Ag(I) centers comprising Ag2 and Ag units with different metal geometries. Other related Ag5 and Ag4 assemblies have also been isolated. The preparation of the [Ag2(isonic)(dppm)2]n n+ polymer (isonic = 4-pyridyl formate, NC5H 4CO2 -) using a ligand transfer pathway from NiCl2(dppm) to AgOTf (OTf = CF3SO3 -) has been identified. The structural outcomes suggested that pyridylcarboxylates of different stereogeometrical and conformational properties can stabilize different oligomeric and topological forms through adaptation to the contrasting demands of the diphosphine and metal. © 2008 American Chemical Society.|
|Source Title:||Inorganic Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on May 23, 2018
WEB OF SCIENCETM
checked on May 8, 2018
checked on May 4, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.