Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2: Phosphine derivative of an electron-deficient linear tetraruthenium cluster

Please use this identifier to cite or link to this item: https://doi.org/10.1021/om2009028

Title:	Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2: Phosphine derivative of an electron-deficient linear tetraruthenium cluster
Authors:	Oh, S.P. Chor, B.Y. Fan, W.Y. Li, Y. Leong, W.K.
Issue Date:	26-Dec-2011
Citation:	Oh, S.P., Chor, B.Y., Fan, W.Y., Li, Y., Leong, W.K. (2011-12-26). Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2: Phosphine derivative of an electron-deficient linear tetraruthenium cluster. Organometallics 30 (24) : 6774-6777. ScholarBank@NUS Repository. https://doi.org/10.1021/om2009028
Abstract:	The reaction of Ru 3(CO) 12 with 1-adamantanecarboxylic acid afforded a purple solid with the formulation Ru 2(CO) 4(μ-OOCAd) 2 (Ad = 1-adamantyl). Reaction of this solid with PPh 3 gave Ru 4(CO) 8(μ-OOCAd) 4(PPh 3) 2, a 64-electron linear tetraruthenium cluster. © 2011 American Chemical Society.
Source Title:	Organometallics
URI:	http://scholarbank.nus.edu.sg/handle/10635/94743
ISSN:	02767333
DOI:	10.1021/om2009028
Appears in Collections:	Staff Publications

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