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https://doi.org/10.1016/j.jorganchem.2005.11.023
| Title: | Regio- and stereoselective addition of carboxylic acids to phenylacetylene catalyzed by cyclopentadienyl ruthenium complexes | Authors: | Ye, S. Leong, W.K. |
Keywords: | Anti-Markovnikov Carboxylic acid Enol esters Phenylacetylene Ruthenium |
Issue Date: | 1-Mar-2006 | Citation: | Ye, S., Leong, W.K. (2006-03-01). Regio- and stereoselective addition of carboxylic acids to phenylacetylene catalyzed by cyclopentadienyl ruthenium complexes. Journal of Organometallic Chemistry 691 (6) : 1117-1120. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.11.023 | Abstract: | The direct addition of carboxylic acids to terminal alkynes such as phenylacetylene in the presence of catalytic amount of [CpRu(CO)2Cl] (1) or [{CpRu(CO)2}2] (2) affords the anti-Markovnikov adducts with high selectivity. In most instances, the E-enol esters are the major products. © 2005 Elsevier B.V. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94709 | ISSN: | 0022328X | DOI: | 10.1016/j.jorganchem.2005.11.023 |
| Appears in Collections: | Staff Publications |
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