Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2006.10.010

Title:	Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene
Authors:	Tan, Y.L.K. Leong, W.K.
Keywords:	Heterometallic clusters Indene Isomers Osmium Ruthenium
Issue Date:	15-Jan-2007
Citation:	Tan, Y.L.K., Leong, W.K. (2007-01-15). Reactivity of the heteronuclear cluster RuOs3(μ-H)2(CO)13 with indene. Journal of Organometallic Chemistry 692 (4) : 768-773. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2006.10.010
Abstract:	The heteronuclear cluster RuOs3(μ-H)2(CO)13 (1) reacts with indene under thermal activation to afford the novel clusters RuOs3(μ-H)(CO)9(μ-CO)2(η 5-C9H7) (3), RuOs3(μ-H)(CO)9(μ3,η 5:η2:η2-C9H7) (4) and Ru2Os3(μ-H)(CO)11(μ3, η5:η2:η2-C9H 7) (5), the latter two possessing indenyl ligands in the μ3,η5:η2:η2 bonding mode. Cluster 5 exists as a mixture of two isomers. The inter-relationship among the clusters has also been investigated. © 2006 Elsevier B.V. All rights reserved.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/94694
ISSN:	0022328X
DOI:	10.1016/j.jorganchem.2006.10.010
Appears in Collections:	Staff Publications

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