Please use this identifier to cite or link to this item:
Title: Reactions of bis(trifluoromethyl)nitroxyl with hydrides of phosphorus and arsenic
Authors: Ang, H.G. 
Koh, C.H.
Issue Date: Jul-1992
Source: Ang, H.G.,Koh, C.H. (1992-07). Reactions of bis(trifluoromethyl)nitroxyl with hydrides of phosphorus and arsenic. Journal of Fluorine Chemistry 58 (1) : 9-15. ScholarBank@NUS Repository.
Abstract: The reactions of bis(trifluoromethyl)nitroxyl with the Group 15 hydrides (CF3)nMH3-n (M = P, As; n = 0, 1) in a ratio of 2:1 proceed rapidly via free-radical mechanisms to afford N,N-bis(trifluoromethyl)hydroxylamine and products which can be rationalised in terms of unstable hydride intermediates (CF3)2NOM(CF3)nH2-n. While the reactions with CF3MH2 (M = P, As) yielded mainly CF3M[ON(CF3)2]2 and (CF3)2NOH, those with AsH3 gave [(CF3)2NO]3As, arsenic metal and (CF3)2NOH. On the other hand, the reactions with PH3 gave a mixture of (CF3)2NOH, (CF3)2NH, hydrogen gas and a polymeric yellow solid. © 1992.
Source Title: Journal of Fluorine Chemistry
ISSN: 00221139
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

checked on Feb 24, 2018

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.