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https://scholarbank.nus.edu.sg/handle/10635/94675
Title: | Reactions of bis(trifluoromethyl)nitroxyl with cyanopentafluorophenylphosphines | Authors: | Ang, H.G. Lee, F.K. |
Issue Date: | Apr-1990 | Citation: | Ang, H.G.,Lee, F.K. (1990-04). Reactions of bis(trifluoromethyl)nitroxyl with cyanopentafluorophenylphosphines. Journal of Fluorine Chemistry 47 (1) : 111-116. ScholarBank@NUS Repository. | Abstract: | Bis(trifluoromethyl)nitroxyl undergoes substitution reactions with (C6F5)3-nP(CN)n (where n = 1, 2, 3) to afford (CF3)2NO(C6F5)3-nP(CN)n-1 respectively, together with the hitherto unreported (CF3)2NOCN. The latter oxidises hydrogen chloride to give N,N-bis(trifluoromethyl)hydroxylamine, chlorine and paracyanogen. © 1990. | Source Title: | Journal of Fluorine Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94675 | ISSN: | 00221139 |
Appears in Collections: | Staff Publications |
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