Probing the transition state via photoelectron and photodetachment spectroscopy of H3O-

Please use this identifier to cite or link to this item: https://doi.org/10.1073/pnas.182297599

Title:	Probing the transition state via photoelectron and photodetachment spectroscopy of H3O-
Authors:	Zhang, D.H. Yang, M. Collins, M.A. Lee, S.-Y.
Issue Date:	3-Sep-2002
Citation:	Zhang, D.H., Yang, M., Collins, M.A., Lee, S.-Y. (2002-09-03). Probing the transition state via photoelectron and photodetachment spectroscopy of H3O-. Proceedings of the National Academy of Sciences of the United States of America 99 (18) : 11579-11582. ScholarBank@NUS Repository. https://doi.org/10.1073/pnas.182297599
Abstract:	The H3O- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 ↔ H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the critical transition-state region. Accurate quantum dynamics calculations of the photoelectron intensity and photodissociation product energies are shown to provide a quantitatively reliable means of interpreting such experimental observations and reveal a detailed picture of the reaction dynamics.
Source Title:	Proceedings of the National Academy of Sciences of the United States of America
URI:	http://scholarbank.nus.edu.sg/handle/10635/94620
ISSN:	00278424
DOI:	10.1073/pnas.182297599
Appears in Collections:	Staff Publications

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