Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/94615
Title: Preparation, characterisation and structures of copper(II) complexes of an asymmetric anti-cancer drug analogue
Authors: Moubaraki, B.
Murray, K.S.
Ranford, J.D. 
Vittal, J.J. 
Wang, X.
Xu, Y.
Issue Date: 21-Oct-1999
Source: Moubaraki, B.,Murray, K.S.,Ranford, J.D.,Vittal, J.J.,Wang, X.,Xu, Y. (1999-10-21). Preparation, characterisation and structures of copper(II) complexes of an asymmetric anti-cancer drug analogue. Journal of the Chemical Society - Dalton Transactions (20) : 3573-3578. ScholarBank@NUS Repository.
Abstract: A series of copper(II) complexes of the anti-cancer drug analogue 1,5-bis(2-pyridylmethylene)thiocarbonohydrazide (H2L) was synthesized from acid solution. The single crystal structures of two asymmetric, binuclear, complexes [{Cu2(HL)(H2PO4)2} 2][NO3]2·2H2O and [{Cu2(HL)(CF3CO2)3}2] and two mononuclear, monomeric complexes [Cu(H3L)(H2O)][ClO4]3·ZH 2O and [Cu(H3L)(NO3)2]NO3 were solved. The binuclear complexes are dimeric with three-atom anion bridges. Selective removal of one copper ion gives mononuclear monomers. The primary magnetic exchange is between copper(II) centres within a planar binuclear unit with weaker interactions via anion or sulfur bridges. © The Royal Society of Chemistry 1999.
Source Title: Journal of the Chemical Society - Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/94615
ISSN: 03009246
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

20
checked on Feb 23, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.