Photochemical reaction of Rh2(CO)4(μ-TPP)(TPP=tetraphenyl-porphyrinato) with pyridine (Py) in benzene. Generation of a mononuclear rhodium(II) porphyrin radical complex Rh(TPP)(Py)

Please use this identifier to cite or link to this item: https://doi.org/10.1007/BF02910888

Title:	Photochemical reaction of Rh2(CO)4(μ-TPP)(TPP=tetraphenyl-porphyrinato) with pyridine (Py) in benzene. Generation of a mononuclear rhodium(II) porphyrin radical complex Rh(TPP)(Py)
Authors:	Huang, J.-W. Ji, L.-N. Hsich, A.-K. Hor, T.S.A.
Issue Date:	Aug-1992
Citation:	Huang, J.-W., Ji, L.-N., Hsich, A.-K., Hor, T.S.A. (1992-08). Photochemical reaction of Rh2(CO)4(μ-TPP)(TPP=tetraphenyl-porphyrinato) with pyridine (Py) in benzene. Generation of a mononuclear rhodium(II) porphyrin radical complex Rh(TPP)(Py). Transition Metal Chemistry 17 (4) : 280-282. ScholarBank@NUS Repository. https://doi.org/10.1007/BF02910888
Abstract:	Photolytic decarbonylation of Rh2(CO)4(TPP) (TPP=tetraphenylporphyrinato) with pyridine (Py) in benzene gives an unusual monomeric RhII radical complex Rh(TPP)(Py), which has been characterised by thermal and spectroscopic measurements and by vapour pressure osmosis. © 1992 Chapman & Hall.
Source Title:	Transition Metal Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/94517
ISSN:	03404285
DOI:	10.1007/BF02910888
Appears in Collections:	Staff Publications

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