Palladium-osmium heterometallic clusters containing N-heterocyclic carbene ligands

Please use this identifier to cite or link to this item: https://doi.org/10.1021/om401031h

Title:	Palladium-osmium heterometallic clusters containing N-heterocyclic carbene ligands
Authors:	Liu, Y. Ganguly, R. Huynh, H.V. Leong, W.K.
Issue Date:	23-Dec-2013
Citation:	Liu, Y., Ganguly, R., Huynh, H.V., Leong, W.K. (2013-12-23). Palladium-osmium heterometallic clusters containing N-heterocyclic carbene ligands. Organometallics 32 (24) : 7559-7563. ScholarBank@NUS Repository. https://doi.org/10.1021/om401031h
Abstract:	The room-temperature reaction of [Os3(CO)12] with [PdCl(allyl)(NHC)], where NHC (N-heterocyclic carbene) = SIPr [N,N′-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene] or IPr [N,N′-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene], afforded Pd-Os mixed metal clusters with formulas of [PdnOs3(CO) 12(NHC)n] (n = 1-3). These are the first examples of Pd-Os heterometallic clusters containing NHC ligands, and they have all been structurally characterized. In all these clusters, the metal cores are raftlike, with carbonyl ligands bridging all the Os-Pd edges. © 2013 American Chemical Society.
Source Title:	Organometallics
URI:	http://scholarbank.nus.edu.sg/handle/10635/94483
ISSN:	15206041
DOI:	10.1021/om401031h
Appears in Collections:	Staff Publications

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