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|Title:||Palladium-osmium heterometallic clusters containing N-heterocyclic carbene ligands|
|Source:||Liu, Y., Ganguly, R., Huynh, H.V., Leong, W.K. (2013-12-23). Palladium-osmium heterometallic clusters containing N-heterocyclic carbene ligands. Organometallics 32 (24) : 7559-7563. ScholarBank@NUS Repository. https://doi.org/10.1021/om401031h|
|Abstract:||The room-temperature reaction of [Os3(CO)12] with [PdCl(allyl)(NHC)], where NHC (N-heterocyclic carbene) = SIPr [N,N′-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene] or IPr [N,N′-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene], afforded Pd-Os mixed metal clusters with formulas of [PdnOs3(CO) 12(NHC)n] (n = 1-3). These are the first examples of Pd-Os heterometallic clusters containing NHC ligands, and they have all been structurally characterized. In all these clusters, the metal cores are raftlike, with carbonyl ligands bridging all the Os-Pd edges. © 2013 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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