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https://scholarbank.nus.edu.sg/handle/10635/94474
| Title: | Palladium(II) and platinum(II) complexes with a novel P-S(O)-P tridentate ligand | Authors: | Siah, S.-Y. Leung, P.-H. Mok, K.F. |
Issue Date: | Dec-1994 | Citation: | Siah, S.-Y.,Leung, P.-H.,Mok, K.F. (1994-12). Palladium(II) and platinum(II) complexes with a novel P-S(O)-P tridentate ligand. Polyhedron 13 (23) : 3253-3255. ScholarBank@NUS Repository. | Abstract: | The syntheses of two square-planar complexes [MCl{(Ph2PCH2CH2)2SO}ClO4 (M = Pd or Pt) have been achieved. X-ray crystal structure analysis of the platinum(II) complex reveals that the tridentate ligand coordinates to platinum via its phosphorus and sulphur donor atoms resulting in the formation of two five-membered chelate rings. A similar structure is assigned to the palladium(II) analogue by spectroscopic studies. Oxygen-metal bonds are not involved in these complexes. © 1994. | Source Title: | Polyhedron | URI: | http://scholarbank.nus.edu.sg/handle/10635/94474 | ISSN: | 02775387 |
| Appears in Collections: | Staff Publications |
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