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Title: Oxidative addition of substituted arsines and stibines with bis(trifluoromethyl)nitroxyl
Authors: Ang, H.G. 
Lien, W.S.
Issue Date: Jun-1980
Source: Ang, H.G.,Lien, W.S. (1980-06). Oxidative addition of substituted arsines and stibines with bis(trifluoromethyl)nitroxyl. Journal of Fluorine Chemistry 15 (6) : 453-470. ScholarBank@NUS Repository.
Abstract: Reactions of bis(trifluoromethyl)nitroxyl with a number of methyl- and trifluoromethyl- substituted arsines and stibines at room temperature lead to the formation of pentavalent arsenic and antimony derivatives, namely (CH3)3-n(CF3)nM[ON(CF3 )2]2 (M = As, n = 0, 1, 2; M = Sb, n = 0, 1). The derivatives yield bis(trifluoromethyl)- hydroxylamine and the corresponding dichlorides on treatment with hydrogen chloride. A free radical mechanism is proposed for the oxidative addition reactions. © 1980.
Source Title: Journal of Fluorine Chemistry
ISSN: 00221139
Appears in Collections:Staff Publications

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