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|Title:||Oxidative addition of substituted arsines and stibines with bis(trifluoromethyl)nitroxyl|
|Authors:||Ang, H.G. |
|Source:||Ang, H.G.,Lien, W.S. (1980-06). Oxidative addition of substituted arsines and stibines with bis(trifluoromethyl)nitroxyl. Journal of Fluorine Chemistry 15 (6) : 453-470. ScholarBank@NUS Repository.|
|Abstract:||Reactions of bis(trifluoromethyl)nitroxyl with a number of methyl- and trifluoromethyl- substituted arsines and stibines at room temperature lead to the formation of pentavalent arsenic and antimony derivatives, namely (CH3)3-n(CF3)nM[ON(CF3 )2]2 (M = As, n = 0, 1, 2; M = Sb, n = 0, 1). The derivatives yield bis(trifluoromethyl)- hydroxylamine and the corresponding dichlorides on treatment with hydrogen chloride. A free radical mechanism is proposed for the oxidative addition reactions. © 1980.|
|Source Title:||Journal of Fluorine Chemistry|
|Appears in Collections:||Staff Publications|
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