Novel interpenetrating polymer network electrolytes

Abstract

A new type of solid polymer electrolyte (SPE) was prepared by sequential interpenetration of cross-linked methoxyoligo (oxyethylene) methacrylate (MOEnM) and poly(methyl methacrylate) (PMMA). When the interpenetrating polymer networks (IPNs) were swollen with liquid electrolyte solutions, they showed structures that were between the chemically cross-linked gel SPEs and the porous SPE. They could swell/hold much more electrolyte solution than the porous SPE. The electrolytes exhibited ionic conductivities in the order of 10-3 S cm-1 at 25°C, and could be useful in many practical electrochemical devices. © 2001 Elsevier Science Ltd.