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https://scholarbank.nus.edu.sg/handle/10635/94142
| Title: | Lathanum Trifluoromethanesulfonate [La(OTf)3] Promoted Indium-Mediated Coupling of Ethyl 4-Bromocrotonate with Carbonyl Compounds in Water | Authors: | Diana, S.-C.H. Sim, K.-Y. Loh, T.-P. |
Issue Date: | 1996 | Citation: | Diana, S.-C.H.,Sim, K.-Y.,Loh, T.-P. (1996). Lathanum Trifluoromethanesulfonate [La(OTf)3] Promoted Indium-Mediated Coupling of Ethyl 4-Bromocrotonate with Carbonyl Compounds in Water. Synlett 1996 (3) : 263-264. ScholarBank@NUS Repository. | Abstract: | Indium mediates the coupling of ethyl 4-bromocrotonate with carbonyl compounds in water to give the corresponding β-hydroxy-α-vinyl carboxylates in good yield and high anti-diastereoselectivity. Furthermore, the use of lanthanide triflate increases the rate and selectivity of the reactions. | Source Title: | Synlett | URI: | http://scholarbank.nus.edu.sg/handle/10635/94142 | ISSN: | 09365214 |
| Appears in Collections: | Staff Publications |
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