Interpenetrating versus Noninterpenetrating (4,4) Nets: Influence of the Size of the Metal and Counter Ions

Please use this identifier to cite or link to this item: https://doi.org/10.1021/cg015510z

Title:	Interpenetrating versus Noninterpenetrating (4,4) Nets: Influence of the Size of the Metal and Counter Ions
Authors:	Ni, Z. Vittal, J.J.
Issue Date:	May-2001
Citation:	Ni, Z., Vittal, J.J. (2001-05). Interpenetrating versus Noninterpenetrating (4,4) Nets: Influence of the Size of the Metal and Counter Ions. Crystal Growth and Design 1 (3) : 195-197. ScholarBank@NUS Repository. https://doi.org/10.1021/cg015510z
Abstract:	Puckered square grid coordination polymers [M(dps)2]X (M = Cu(I), X = ClO4 (1), PF6 (2); M = Ag(I), X = PF6 (3), CF3SO3 (4); dps = 4,4′-dipyridylsulfide) have been synthesized and characterized in the solid state by X-ray crystallography. Of these, the cations in 3 and 4 were found to interpenetrate while 1 and 2 were not. However, the anions greatly influence the conformation of the puckered square grids in 1 and 2.
Source Title:	Crystal Growth and Design
URI:	http://scholarbank.nus.edu.sg/handle/10635/94077
ISSN:	15287483
DOI:	10.1021/cg015510z
Appears in Collections:	Staff Publications

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