Please use this identifier to cite or link to this item: https://doi.org/10.1021/cg0505766
Title: Inorganic complexes retain diethyl ether well above its boiling point through OH2⋯OEt2 hydrogen bonding
Authors: Tian, L. 
Vittal, J.J. 
Issue Date: Apr-2006
Source: Tian, L., Vittal, J.J. (2006-04). Inorganic complexes retain diethyl ether well above its boiling point through OH2⋯OEt2 hydrogen bonding. Crystal Growth and Design 6 (4) : 822-824. ScholarBank@NUS Repository. https://doi.org/10.1021/cg0505766
Abstract: The structures of [M(2,2′-bpy)(SC{O}Ph)3(H 2O)]·Et2O (M = La (1), Pr (2), and Sm (3); 2,2′-bpy = 2,2′-bipyridine) have an eight-membered hydrogen-bonded ring formed between two diethyl ether (Et2O) and two aqua ligands, and they retain Et2O above its boiling point despite the presence of channels in the lattice for Et2O to escape. The inception temperatures for the weight loss of Et2O, 82, 69, and 51 °C 1, 2, and 3, respectively, appear to be controlled by the size of the metal ions. Et2O-free solid 1 is able to take back Et2O quantitatively. © 2006 American Chemical Society.
Source Title: Crystal Growth and Design
URI: http://scholarbank.nus.edu.sg/handle/10635/94058
ISSN: 15287483
DOI: 10.1021/cg0505766
Appears in Collections:Staff Publications

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