Please use this identifier to cite or link to this item: https://doi.org/10.1002/zaac.200900243
Title: Hydrothermal synthesis of a 3D polymeric cobalt(II) carboxylate derivative from 1,2,4,5-benzenetetracarbonitrile
Authors: Sun, B.
Chen, X.
Ang, S.G. 
Li, Z.
Jiang, X.
Keywords: 1,2,4,5-Benzenetetracarbonitrile
Cobalt
Hydrothermal synthesis
Magnetic properties
Polymers
Issue Date: Dec-2009
Citation: Sun, B., Chen, X., Ang, S.G., Li, Z., Jiang, X. (2009-12). Hydrothermal synthesis of a 3D polymeric cobalt(II) carboxylate derivative from 1,2,4,5-benzenetetracarbonitrile. Zeitschrift fur Anorganische und Allgemeine Chemie 635 (15) : 2375-2377. ScholarBank@NUS Repository. https://doi.org/10.1002/zaac.200900243
Abstract: The metal-organic complexes Co2(terpy)2(btec)-H 2O 1 (terpy = 2,2′:6′,2″-terpyridine, btec = 1,2,4,5-benzenetetracarboxylate) was synthesized by hydrothermal synthesis method, using 1,2,4,5-ben-zenetetracarbonitrile, terpy and CoAc 24H2O. Single crystal X-ray diffraction showed that each btec4-ligand links four CoIIatoms and each Co IIatom links to two btec4-ligands forming a 1D double-chain structure. Furthermore, the chains pack together through short face-face π-π interactions forming a 3D supramolecular structure. Additionally, the magnetic measurements show antiferromagnetic interactions among metal ions for compound 1. © 2009 WILEYVCH Verlag GmbH & Co. KGaA.
Source Title: Zeitschrift fur Anorganische und Allgemeine Chemie
URI: http://scholarbank.nus.edu.sg/handle/10635/93995
ISSN: 00442313
DOI: 10.1002/zaac.200900243
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