Hydrothermal synthesis of a 3D polymeric cobalt(II) carboxylate derivative from 1,2,4,5-benzenetetracarbonitrile

Please use this identifier to cite or link to this item: https://doi.org/10.1002/zaac.200900243

Title:	Hydrothermal synthesis of a 3D polymeric cobalt(II) carboxylate derivative from 1,2,4,5-benzenetetracarbonitrile
Authors:	Sun, B. Chen, X. Ang, S.G. Li, Z. Jiang, X.
Keywords:	1,2,4,5-Benzenetetracarbonitrile Cobalt Hydrothermal synthesis Magnetic properties Polymers
Issue Date:	Dec-2009
Citation:	Sun, B., Chen, X., Ang, S.G., Li, Z., Jiang, X. (2009-12). Hydrothermal synthesis of a 3D polymeric cobalt(II) carboxylate derivative from 1,2,4,5-benzenetetracarbonitrile. Zeitschrift fur Anorganische und Allgemeine Chemie 635 (15) : 2375-2377. ScholarBank@NUS Repository. https://doi.org/10.1002/zaac.200900243
Abstract:	The metal-organic complexes Co2(terpy)2(btec)-H 2O 1 (terpy = 2,2′:6′,2″-terpyridine, btec = 1,2,4,5-benzenetetracarboxylate) was synthesized by hydrothermal synthesis method, using 1,2,4,5-ben-zenetetracarbonitrile, terpy and CoAc 24H2O. Single crystal X-ray diffraction showed that each btec4-ligand links four CoIIatoms and each Co IIatom links to two btec4-ligands forming a 1D double-chain structure. Furthermore, the chains pack together through short face-face π-π interactions forming a 3D supramolecular structure. Additionally, the magnetic measurements show antiferromagnetic interactions among metal ions for compound 1. © 2009 WILEYVCH Verlag GmbH & Co. KGaA.
Source Title:	Zeitschrift fur Anorganische und Allgemeine Chemie
URI:	http://scholarbank.nus.edu.sg/handle/10635/93995
ISSN:	00442313
DOI:	10.1002/zaac.200900243
Appears in Collections:	Staff Publications

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