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https://doi.org/10.1016/S1387-7003(03)00048-0
| Title: | Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3 O19}·4.5H2O | Authors: | Asnani, M. Ramanan, A. Vittal, J.J. |
Keywords: | Hydrothermal synthesis Single crystal X-ray diffraction Vanadium borophosphate |
Issue Date: | 1-May-2003 | Citation: | Asnani, M., Ramanan, A., Vittal, J.J. (2003-05-01). Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3 O19}·4.5H2O. Inorganic Chemistry Communications 6 (5) : 589-592. ScholarBank@NUS Repository. https://doi.org/10.1016/S1387-7003(03)00048-0 | Abstract: | Hydrothermal reaction of VOPO4·2H2O and [Co(en)3]Cl3 in sealed borosilicate glass tube yielded a vanadium (V) borophosphate cluster based solid, [Co(en)3][enH2]{V3BP3 O19}·4.5H2O (VBPO). Crystal data: monoclinic space group, P21/c, Z = 4, a = 12.0709(7), b = 14.2261(8) and c = 18.1104(9) Å, β = 95.067(1)0°, V = 3097.8(3) Å3. Single crystal X-ray diffraction studies revealed that discrete [V3BP3O19] clusters are linked to counter cations and water molecules through a complex hydrogen bonding network. © 2003 Elsevier Science B.V. All rights reserved. | Source Title: | Inorganic Chemistry Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/93994 | ISSN: | 13877003 | DOI: | 10.1016/S1387-7003(03)00048-0 |
| Appears in Collections: | Staff Publications |
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