Please use this identifier to cite or link to this item: https://doi.org/10.1016/S1387-7003(03)00048-0
Title: Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3 O19}·4.5H2O
Authors: Asnani, M.
Ramanan, A.
Vittal, J.J. 
Keywords: Hydrothermal synthesis
Single crystal X-ray diffraction
Vanadium borophosphate
Issue Date: 1-May-2003
Citation: Asnani, M., Ramanan, A., Vittal, J.J. (2003-05-01). Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3 O19}·4.5H2O. Inorganic Chemistry Communications 6 (5) : 589-592. ScholarBank@NUS Repository. https://doi.org/10.1016/S1387-7003(03)00048-0
Abstract: Hydrothermal reaction of VOPO4·2H2O and [Co(en)3]Cl3 in sealed borosilicate glass tube yielded a vanadium (V) borophosphate cluster based solid, [Co(en)3][enH2]{V3BP3 O19}·4.5H2O (VBPO). Crystal data: monoclinic space group, P21/c, Z = 4, a = 12.0709(7), b = 14.2261(8) and c = 18.1104(9) Å, β = 95.067(1)0°, V = 3097.8(3) Å3. Single crystal X-ray diffraction studies revealed that discrete [V3BP3O19] clusters are linked to counter cations and water molecules through a complex hydrogen bonding network. © 2003 Elsevier Science B.V. All rights reserved.
Source Title: Inorganic Chemistry Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/93994
ISSN: 13877003
DOI: 10.1016/S1387-7003(03)00048-0
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

8
checked on Jul 18, 2018

WEB OF SCIENCETM
Citations

8
checked on Jun 4, 2018

Page view(s)

44
checked on Apr 20, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.