HMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η6-C6Me6, Cp* = η5-C5Me5)

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2005.10.043

Title:	HMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η6-C6Me6, Cp* = η5-C5Me5)
Authors:	Kuan, S.L. Leong, W.K. Goh, L.Y. Webster, R.D.
Keywords:	(Mercaptomethimazolyl)borate Cp*/(HMB)ruthenium Electrochemistry Scorpionate Structures
Issue Date:	15-Feb-2006
Citation:	Kuan, S.L., Leong, W.K., Goh, L.Y., Webster, R.D. (2006-02-15). HMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η6-C6Me6, Cp* = η5-C5Me5). Journal of Organometallic Chemistry 691 (5) : 907-915. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.10.043
Abstract:	The reactions of [(HMB)RuCl2]2 with K[HB(mt) 3] and Na[H2B(mt)2] (mt = N-methyl-2- mercaptoimidazol-1-yl) led to the isolation of [(HMB)Ru{HB(mt)3}]Cl (1) (ca. 66% yield) and [(HMB)Ru{H2B(mt)2}]Cl (2) (ca. 70% yield), respectively. The reaction of [CpRuOMe]2 with Na[H2B(mt)2] yielded CpRu[H2B(mt) 2] (3) (ca. 85% yield). Single crystal X-ray diffraction analyses were carried out on all three complexes, together with cyclic voltammetric measurements.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/93962
ISSN:	0022328X
DOI:	10.1016/j.jorganchem.2005.10.043
Appears in Collections:	Staff Publications

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