Please use this identifier to cite or link to this item:
|Title:||High-performance hybrid solar cell made from CdSe/CdTe nanocrystals supported on reduced graphene oxide and PCDTBT|
|Source:||Tong, S.W., Mishra, N., Su, C.L., Nalla, V., Wu, W., Ji, W., Zhang, J., Chan, Y., Loh, K.P. (2014-04-02). High-performance hybrid solar cell made from CdSe/CdTe nanocrystals supported on reduced graphene oxide and PCDTBT. Advanced Functional Materials 24 (13) : 1904-1910. ScholarBank@NUS Repository. https://doi.org/10.1002/adfm.201303010|
|Abstract:||Core/shell tetrapods synthesized from CdSe and CdTe exhibit a type II band offset that induces separation of charge upon photoexcitation and localizes carriers to different regions of the tetrahedral geometry. CdSe/CdTe nanocrystals immobilized on oleylamine-functionalized reduced graphene oxide (rGO) sheets can be homogeneously mixed with an organic dye (PCDTBT) to form donor-acceptor dispersed heterojunctions and exhibit a high power conversion efficiency of ∼3.3% in solar cell devices. The near-IR light absorbing type II nanocrystals complement the absorption spectrum of the visible light-absorbing organics. The high efficiency is attributed to the amine-functionalized rGO sheets, which allow intimate contact with the nanocrystals and efficient dispersal in the organic matrix, contributing to highly efficient charge separation and transfer at the nanocrystal, rGO, and polymer interfaces. A chemically mediated way of controlling nanoscale morphologies in a composite is demonstrated by immobilizing CdSe/CdTe nanocrystals on oleylamine-functionalized reduced graphene oxide (rGO) sheets. The tetrapod-rGO can be homogeneously mixed with an organic dye (PCDTBT) to form donor-acceptor dispersed heterojunctions and exhibit a high power-conversion efficiency of ∼3.3% in a solar cell device. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.|
|Source Title:||Advanced Functional Materials|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 23, 2018
WEB OF SCIENCETM
checked on Jan 8, 2018
checked on Jan 22, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.