Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2007.02.001
Title: Ditertiary phosphine derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13
Authors: Tan, Y.L.K.
Leong, W.K. 
Keywords: Ditertiary phosphines
Heterometallic
Isomers
Osmium
Ruthenium
Issue Date: 1-May-2007
Citation: Tan, Y.L.K., Leong, W.K. (2007-05-01). Ditertiary phosphine derivatives of the heteronuclear cluster RuOs3(μ-H)2(CO)13. Journal of Organometallic Chemistry 692 (11) : 2253-2269. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2007.02.001
Abstract: The heteronuclear cluster RuOs3(μ-H)2(CO)13 (1) reacted readily with a number of ditertiary phosphines under chemical activation with trimethylamine-N-oxide. The solid-state and solution structures of these derivatives have been examined. Six structural types have been characterized crystallographically, including one in which a phenyl group migrates from the ditertiary phosphine ligand to the metal framework. There are many more isomers present in solution, most of which are rapidly inter-converting via hydride migrations. © 2006 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/93622
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2007.02.001
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