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|Title:||Cytotoxic polyprenylated benzoylphloroglucinol derivatives with an unusual adamantyl skeleton from Hypericum sampsonii (Guttiferae)|
|Authors:||Hu, L.H. |
|Citation:||Hu, L.H.,Sim, K.Y. (1999-09-23). Cytotoxic polyprenylated benzoylphloroglucinol derivatives with an unusual adamantyl skeleton from Hypericum sampsonii (Guttiferae). Organic Letters 1 (6) : 879-882. ScholarBank@NUS Repository.|
|Abstract:||(equation presented) The structures of sampsoniones I and J, isolated from the aerial parts of the Chinese medicinal plant Hypericum sampsonii, have been elucidated by detailed spectral analysis. They are complex adamantyl derivatives, and sampsonione I is the first polyprenylated benzoylphloroglucinol derivative with the unique caged tetracyclo[220.127.116.11,11.03,8]tetradecane-2,12,14-trione skeleton. Cytotoxic sampsonione I has also been obtained by the biomimetic transformation of sampsonione J.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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