Please use this identifier to cite or link to this item: https://doi.org/10.1007/BF01247244
Title: Crystal structures of 3,5,5′-trichloro-2,2′-bithiophene and 3,3′,5,5′-tetrachloro-2,2′-bithiophene
Authors: Mok, K.F. 
Ng, S.C. 
Novak, I. 
Huang, H.H. 
Issue Date: Oct-1993
Source: Mok, K.F., Ng, S.C., Novak, I., Huang, H.H. (1993-10). Crystal structures of 3,5,5′-trichloro-2,2′-bithiophene and 3,3′,5,5′-tetrachloro-2,2′-bithiophene. Journal of Crystallographic and Spectroscopic Research 23 (10) : 799-803. ScholarBank@NUS Repository. https://doi.org/10.1007/BF01247244
Abstract: The crystal structures of 3,5,5′-trichloro-2,2′-bithiophene (I) and 3,3′,5,5′-tetrachloro-2,2′-bithiophene (II) have been determined by single crystal X-ray diffraction techniques. Both I and II crystallize in the monoclinic crystal system. For I, a=3.895(2), b=11.928(2), c=10.701(2)Å, β=97.70(1)°, space group P21, Z=2 and for II, a=8.942(2), b=3.900(2), c=15.180(2)Å, β=92.30(1)°, space group P21/n, Z=2. The structures have been solved by direct methods and all nonhydrogen atoms refined with anisotropic thermal parameters. For I the final residual is 0.035 (all 1185 independent reflections, Mo Kα radiation) and for II, 0.034 (all 1209 independent reflections, Mo Kα radiation). Both I and II have the anti conformation but I has a torsion angle of 3.4(5)° between the two thiophene rings while II is completely planar. © 1993 Plenum Publishing Corporation.
Source Title: Journal of Crystallographic and Spectroscopic Research
URI: http://scholarbank.nus.edu.sg/handle/10635/93496
ISSN: 02778068
DOI: 10.1007/BF01247244
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