Please use this identifier to cite or link to this item:
|Title:||Crystal structures and characterizations of (nitrato-O) (nitrato-O,O′)(η6-hexamethylbenzene)ruthenium(II) and di(trifluoroacetato-O)(H2O-O)(η6-hexamethylbenzene) ruthenium(II)|
|Citation:||Lu, X.L., Leong, W.K., Goh, L.Y., Hor, T.S.A., Vittal, J.J. (2005). Crystal structures and characterizations of (nitrato-O) (nitrato-O,O′)(η6-hexamethylbenzene)ruthenium(II) and di(trifluoroacetato-O)(H2O-O)(η6-hexamethylbenzene) ruthenium(II). Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry 35 (10) : 743-746. ScholarBank@NUS Repository. https://doi.org/10.1080/15533170500360164|
|Abstract:||The title complexes [(HMB)Ru(NO3)2] (HMB = η6-C6Me6) (1) and [(HMB)Ru(O 2CCF3)2(H2O)] (2) were spectroscopically characterized and their structures were determined by single-crystal diffraction analysis. In both compounds, the Ru atom is η6-coordinated to a hexamethylbenzene ring and three oxygen donor atoms in a "three-legged piano stool" arrangement. In the asymmetric unit of 1, ruthenium atom is coordinated to two nitrato ligands, one of which is η1-O coordinated and the second bidentate via both oxygen atoms; while in the symmetric unit of 2, two disordered trifluoroacetate ligands are monodentate, symmetrically bound to the ruthenium atom, and the pseudo-octahedral geometry is completed by an oxygen atom from a H2O molecule, which is hydrogen-bonded to both acetate ligands. Copyright © 2005 Taylor & Francis, Inc.|
|Source Title:||Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Oct 12, 2018
WEB OF SCIENCETM
checked on Oct 3, 2018
checked on Sep 21, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.