Please use this identifier to cite or link to this item: https://doi.org/10.1021/ja402630g
Title: Cp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer
Authors: Huang, S.-L.
Lin, Y.-J.
Hor, T.S.A. 
Jin, G.-X.
Issue Date: 5-Jun-2013
Source: Huang, S.-L., Lin, Y.-J., Hor, T.S.A., Jin, G.-X. (2013-06-05). Cp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer. Journal of the American Chemical Society 135 (22) : 8125-8128. ScholarBank@NUS Repository. https://doi.org/10.1021/ja402630g
Abstract: A series of CpRh-based functional metallarectangles have been synthesized from metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link architectures. All these complexes are intact in solution, as evident from ESI-MS spectroscopic analysis. Arising from the combination of open Cu centers and favorable cavity space, {(CpRh)4(bpe) 2[Cu(opba)·2MeOH]2}4(OTf)·6MeOH shows extraordinary catalytic abilities with high efficiency and wide substrate selectivity in the acyl-transfer reaction. © 2013 American Chemical Society.
Source Title: Journal of the American Chemical Society
URI: http://scholarbank.nus.edu.sg/handle/10635/93406
ISSN: 00027863
DOI: 10.1021/ja402630g
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