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|Title:||Convenient entry to mono- and dinuclear palladium(II) benzothiazolin-2- ylidene complexes and their activities toward Heck Coupling|
|Authors:||Yen, S.K. |
|Citation:||Yen, S.K., Koh, L.L., Hahn, F.E., Huynh, H.V., Hor, T.S.A. (2006-10-09). Convenient entry to mono- and dinuclear palladium(II) benzothiazolin-2- ylidene complexes and their activities toward Heck Coupling. Organometallics 25 (21) : 5105-5112. ScholarBank@NUS Repository. https://doi.org/10.1021/om060510n|
|Abstract:||Under solventless conditions, benzothiazole reacts with benzyl bromide to give near-quantitative yield of the salt W-benzylbenzothiazolium bromide (A), which is a convenient air-stable heterocyclic carbene precursor. Treatment of A with Pd(OAc)2 in CH3CN affords the bis(carbene) complex cis-[PdBr2(NHC)2] (1) (NHC = N-benzylbenzothiazolin-2- ylidene). In DMSO, this reaction yields an unprecedented dinuclear N,S-heterocyclic carbene complex, [PdBr2(NHC)]2 (2). Complex 2 undergoes bridge cleavage reactions with CH3CN and DMF to give the mononuclear and solvated monocarbene complexes trans-[PdBr 2(NHC)(Solv)] [Solv = CH3CN (3) and DMF (4)]. All compounds have been fully characterized by 1H and 13C NMR spectroscopy, ESI or FAB mass spectrometry, and elemental analysis. The molecular structures of A and 1-4 have been determined by X-ray single-crystal diffraction. The catalytic activities of 1-4 toward Mizoroki-Heck coupling reactions of aryl bromides with tert-butyl acrylate are described and compared. © 2006 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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