Please use this identifier to cite or link to this item: https://doi.org/10.1021/ja311202e
Title: C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization
Authors: Chen, F.
Tan, C.K.
Yeung, Y.-Y. 
Issue Date: 30-Jan-2013
Citation: Chen, F., Tan, C.K., Yeung, Y.-Y. (2013-01-30). C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization. Journal of the American Chemical Society 135 (4) : 1232-1235. ScholarBank@NUS Repository. https://doi.org/10.1021/ja311202e
Abstract: A catalytic asymmetric bromocyclization of trisubstituted olefinic amides that uses a C2-symmetric mannitol-derived cyclic selenium catalyst and a stoichiometric amount of N-bromophthalimide is reported. The resulting enantioenriched pyrrolidine products, which contain two stereogenic centers, can undergo rearrangement to yield 2,3-disubstituted piperidines with excellent diastereoselectivity and enantiospecificity. © 2013 American Chemical Society.
Source Title: Journal of the American Chemical Society
URI: http://scholarbank.nus.edu.sg/handle/10635/93221
ISSN: 00027863
DOI: 10.1021/ja311202e
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