Please use this identifier to cite or link to this item:
https://doi.org/10.1021/ja311202e
| Title: | C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization | Authors: | Chen, F. Tan, C.K. Yeung, Y.-Y. |
Issue Date: | 30-Jan-2013 | Citation: | Chen, F., Tan, C.K., Yeung, Y.-Y. (2013-01-30). C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization. Journal of the American Chemical Society 135 (4) : 1232-1235. ScholarBank@NUS Repository. https://doi.org/10.1021/ja311202e | Abstract: | A catalytic asymmetric bromocyclization of trisubstituted olefinic amides that uses a C2-symmetric mannitol-derived cyclic selenium catalyst and a stoichiometric amount of N-bromophthalimide is reported. The resulting enantioenriched pyrrolidine products, which contain two stereogenic centers, can undergo rearrangement to yield 2,3-disubstituted piperidines with excellent diastereoselectivity and enantiospecificity. © 2013 American Chemical Society. | Source Title: | Journal of the American Chemical Society | URI: | http://scholarbank.nus.edu.sg/handle/10635/93221 | ISSN: | 00027863 | DOI: | 10.1021/ja311202e |
| Appears in Collections: | Staff Publications |
Show full item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.