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https://scholarbank.nus.edu.sg/handle/10635/93205
| Title: | Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2 | Authors: | Leong, W.K. Einstein, F.W.B. Pomeroy, R.K. |
Issue Date: | 15-Jan-1997 | Citation: | Leong, W.K.,Einstein, F.W.B.,Pomeroy, R.K. (1997-01-15). Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2. Acta Crystallographica Section C: Crystal Structure Communications 53 (1) : 22-24. ScholarBank@NUS Repository. | Abstract: | The title compound, octacarbonyl-1κ4C,2κ 4C-dihydrido-1κH,2κH-bis(phenyl-3κC) germaniumdiosmium(2 Ge-Os), [Os2(H)2(CO)8{Ge(C6H 5)2}], is the first cluster containing a single Os-E-Os (E = Ge, Sn or Pb) chain to be structurally characterized. The molecule possesses approximate C2 symmetry. The Os-Ge-Os metal chain is bent and the Os-Ge bonds [2.599(2) and 2.614 (2) Å] are the longest yet known. | Source Title: | Acta Crystallographica Section C: Crystal Structure Communications | URI: | http://scholarbank.nus.edu.sg/handle/10635/93205 | ISSN: | 01082701 |
| Appears in Collections: | Staff Publications |
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