Please use this identifier to cite or link to this item: https://doi.org/10.1021/om700949s
Title: Benzenimidazole-functionalized imidazolium-based N-heterocyclic carbene complexes of silver(I) and palladium(II): Isolation of a Ag3 intermediate toward a facile transmetalation and suzuki coupling
Authors: Li, F. 
Bai, S. 
Andy Hor, T.S. 
Issue Date: 25-Feb-2008
Source: Li, F., Bai, S., Andy Hor, T.S. (2008-02-25). Benzenimidazole-functionalized imidazolium-based N-heterocyclic carbene complexes of silver(I) and palladium(II): Isolation of a Ag3 intermediate toward a facile transmetalation and suzuki coupling. Organometallics 27 (4) : 672-677. ScholarBank@NUS Repository. https://doi.org/10.1021/om700949s
Abstract: A new benzenimidazole-functionalized imidazolium-based N-heterocyclic carbene complex of Pd(II) has been prepared from facile transmetalation via a Ag(I) precursor. The latter was obtained from a condensation reaction between Ag2O and benzenimidazolium salt. Single-crystal X-ray crystallography revealed an unusual trinuclear AgSCl2(M-Cl2(μ-N-C) 2 (N-C = 3-methyl-1-(l-ethyl-2-methylbenzoyl)imidazolin-2-ylidene) intermediate in which the central carbene-supported Ag(I) is flanked by two imidazolecoordinated Ag(I). The hybrid ligand (N-C), carrying two heterodonors of benzenimidazole and carbene, is bridging in Ag(I) but chelating in Pd(II), The latter mononuclear PdCl2(η-N-C) is active toward Suzuki-Miyaura coupling of aryl bromides and boronic acids, giving a TON up to 11 750 within 4 h at rt. © 2008 American Chemical Society.
Source Title: Organometallics
URI: http://scholarbank.nus.edu.sg/handle/10635/93164
ISSN: 02767333
DOI: 10.1021/om700949s
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