Please use this identifier to cite or link to this item:
|Title:||An unusual interweaving in a 3-fold interpenetrated pillared-layer Zn(II) coordination polymer with a long spacer ligand|
|Source:||Park, I.-H., Kim, K., Lee, S.S., Vittal, J.J. (2012-07-03). An unusual interweaving in a 3-fold interpenetrated pillared-layer Zn(II) coordination polymer with a long spacer ligand. Crystal Growth and Design 12 (7) : 3397-3401. ScholarBank@NUS Repository. https://doi.org/10.1021/cg300598y|
|Abstract:||This communication describes a unique interweaving of a pyridyl-based long linear spacer ligand, 1,4-bis[2-(4-pyridyl)ethenyl]benzene (bpeb), in the triply interpenetrated pillar-layer porous coordination polymer [Zn 2(ndc) 2(bpeb)]•DMF•3H 2O(where ndc = 2,6-naphthalenedicarboxylate) containing a paddle-wheel secondary building unit (SBU) with α-Po topology. When the dicarboxylate is changed diethylpyrocarbonate (DEPC) fromndc to biphenyl-4,4′-dicarboxylate (bpdc), the reaction furnished a completely different 3-fold interpenetrating three-dimensional coordination polymer [Zn 3(bpdc) 3(bpeb)] •0.5DMSO•1.5H 2O having a uninodal eight connected network structure with hexagonal bipyramidal SBUs. © 2012 American Chemical Society.|
|Source Title:||Crystal Growth and Design|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 15, 2018
WEB OF SCIENCETM
checked on Feb 7, 2018
checked on Feb 20, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.