Please use this identifier to cite or link to this item: https://doi.org/10.1021/ol010246o
Title: An anionic C3-C5 ring expansion of β-ketocyclopropanes to cyclopentenols
Authors: Greatrex, B.W.
Taylor, D.K.
Tiekink, E.R.T. 
Issue Date: 2002
Citation: Greatrex, B.W., Taylor, D.K., Tiekink, E.R.T. (2002). An anionic C3-C5 ring expansion of β-ketocyclopropanes to cyclopentenols. Organic Letters 4 (2) : 221-224. ScholarBank@NUS Repository. https://doi.org/10.1021/ol010246o
Abstract: Chemical equation presented When treated with base, β-ketocyclopropylcarboxylates ring-open to initially afford either cis or trans α,β-unsaturated ketones. The cis isomer undergoes an intramolecular aldol reaction to afford allylic cyclopentenols in high yield and excellent diastereoselectivity. Choice of base is key to a successful outcome.
Source Title: Organic Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/93082
ISSN: 15237060
DOI: 10.1021/ol010246o
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

9
checked on Jun 16, 2018

WEB OF SCIENCETM
Citations

6
checked on May 30, 2018

Page view(s)

36
checked on Jun 1, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.