Please use this identifier to cite or link to this item: https://doi.org/10.1002/ejic.200900049
Title: A Cyclometallated (Azobenzene)palladium(II) complex of 1,4,7- trithiacyclononane: Synthesis and reactivity with thioether-dithiolate metalloligands, single-crystal X-ray diffraction analyses and electrochemical studies
Authors: Shin, R.Y.C.
Goh, C.
Goh, L.Y. 
Webster, R.D.
Li, Y.
Keywords: Crown compounds
Heterometallic complexes
Palladium
Ruthenium
S ligands
Issue Date: May-2009
Citation: Shin, R.Y.C., Goh, C., Goh, L.Y., Webster, R.D., Li, Y. (2009-05). A Cyclometallated (Azobenzene)palladium(II) complex of 1,4,7- trithiacyclononane: Synthesis and reactivity with thioether-dithiolate metalloligands, single-crystal X-ray diffraction analyses and electrochemical studies. European Journal of Inorganic Chemistry (15) : 2282-2293. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.200900049
Abstract: The treatment of [jPd(C6H4N=NC6H 5)(μ-Cl)j2](5) with AgPF6/NH 4PF6 in acetone, followed by the addition of two molar equivalents of 1,4,7-trithiacyclononane (9S3), gives the deep red complex [Pd(C6H4N=NC6H5)(9S3)][PF 6](6A)in high yield, whereas the direct reaction of 5 with two molar equivalents of 9S3 gives [Pd(C6H4N=NC6H 5)(9S3)][Pd- (C6H4N=NC6H 5)Cl2](6B) in quantitative yield based on 5. The subsequent reaction of 5 and 6A with the metalloligand [(HMB)Ru n{r3-tpdt}] [3; HMB = n6-C6Me 6, tpdt = S(CH2- CH2S-)2] results in displacement of the chloride and 9S3 ligands, respectively, to give the Ru-Pd heterobimetallic complex [{(HMB)RuII(̂-n 2:n3-tpdt)jjPd(C6H4nf>N= NC
Source Title: European Journal of Inorganic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/92933
ISSN: 14341948
DOI: 10.1002/ejic.200900049
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